Arsenal have played Villareal CF 1 times in competitive football, winning 0, drawing 1 and losing 0, first meeting on 25 Apr 2006 and most recently on 25 Apr 2006. Every meeting is listed below.
| Date | Season | Competition | Venue | Opponent | Score | Scorers | Att |
|---|---|---|---|---|---|---|---|
| 25 Apr 2006 | 2005–06 | Champions League | A | Villareal CF | 0–0 | 22,000 |